Suite 400 Northbrook, IL 60062 T 1-800-524-0132 PCS Sales (Canada), Inc. (A Subsidiary of Nutrien) Suite 500 122 1st Avenue South Saskatoon, Saskatchewan Canada S7K 7G3 T 1-800-542-0132 sds@nutrien.com - www.nutrien.com Ammonia, Anhydrous DOT: Department of Transportation See Section 13, Disposal Considerations. CAS REGISTRY NO: 7664-41-7. Call a doctor/physician and seek medical attention for severe exposure or if symptoms persist. Moreover, it should not be assumed that every acceptable test or safety procedure or method, precaution, equipment or device is contained within, or that abnormal or unusual circumstances may not warrant or suggest further requirements or additional procedures. Anhydrous ammonia is transferred and stored as a liquefied, compressed gas and is relatively easy to handle with readily available equipment designed for ammonia service. : SDS-002-CLP Air Liquide UK Ltd. Station Road Coleshill B46 1JY Birmingham United Kingdom 01675 462424 EN (English) SDS Ref. Recommended use Manufacture of fertilisers, sodium cyanide and explosives. It is used in the production of fertilizers, explosives and polymers. Refer to 49 CFR 172.328, Cargo Tanks for additional marking requirements. Wear protective gloves, protective clothing, eye protection, face protection. A positive pressure SCBA is required for entry into ammonia atmospheres at or above 300 ppm (IDLH). Use water spray to keep fire-exposed containers cool and control vapors. Anhydrous ammonia is one of the most efficient and widely used sources of nitrogen for plant growth. Aquatic plants: LOEC = 0.5-500 mg NH3-N/L. Aqua Ammonia Industrial Grade Product Specification • Ammonia can be used in … Pulmonary edema may follow chemical bronchitis. endobj 6 0 obj <>stream SAFETY DATA SHEET GHS product identifier Other means of identification Product type Section 1. ACA's HMIS® hazard rating scheme is designed to be GENERAL: Product Name: Ammonia, Anhydrous In the United States, ammonia is primarily used as a feedstock to produce nitrogen fertilizers, such as urea an ammonium sulfate, and is also directly applied to soil as a fertilizer. Environmental Fate Information: Ammonia dissipates relatively quickly in ambient air and rapidly returns to the soil via combination with sulfate ions or washout by rainfall. Page 1 of 9 . PEL: Permissible Exposure Limit Stay upwind and use water spray downwind of container to absorb the evolved gas. It is used and stored under high pressures, which requires specially designed and well-maintained equipment. Only trained persons should handle anhydrous ammonia. Anhydrous ammonia is a highly effective fertilizer that helps farmers feed our growing population and replenish nutrients in the soil. Gases Under Pressure (Liquefied gas) Refer to 29 CFR 1910.133 for OSHA eye protection requirements. Ammonia Chemical family Corrosive, caustic, reactive gas Synonyms Anhydrous ammonia, R717 CAS No. Store locked up. Contains gas under pressure; may explode if heated. Section 8. Classified as Resource Conservation and Recovery Act (RCRA) Hazardous Waste due to corrosivity with designation D002, if disposed of in original form. It is the responsibility of the employer to Reagent for chemical vapor deposition of TiN. Extreme exposure may result in death from spasm, inflammation or edema. Material Name: AMMONIA, ANHYDROUS SDS ID: MAT01050 _____ Page 3 of 9 Issue date: 2020-07-11 Revision 6.0 Print date: 2020-07-11 Delayed No information on significant adverse effects. ... (See Ammonia Solutions SDS) Advanced treatment: In cases of respiratory compromise secure airway and respiration via endotracheal intubation. Nickel refinement. (OSHA) revised Hazard Communication Standard (HCS). Acute toxicity to invertebrates: 48 h LC50 = 2.94 mg un-ionized NH3-N/L. May drink orange juice, citrus juice or diluted vinegar (1:4) to counteract ammonia. Anhydrous Ammonia (SDS: P-16) Safety Data Sheet SDS: P-16 Version: 2 Revision Date: 11/07/2016 Page 3 / 9 SECTION 5: FIRE FIGHTING MEASURES Extinguishing Media Suitable Extinguishing Media: Water spray, fog. May cause damage to organs through prolonged or repeated exposure. Section 2: Added note regarding the Hazardous Materials Identification System (HMIS). 0.682 at 28 °F (Compared to water at 39 °F). Telephone (General): 215-322-1238 Eyelids should be held apart and away from eyeball for thorough rinsing. SYNONYMS: Ammonia Any anhydrous ammonia contact with our bodies could cause tissue dehydration, caustic burns as well as frostbite. It has also been used for adjusting pH during the synthesis of magnetite-hematite mixture by combustion methods. Hazards identification : 302 5/17 11/20/2012 Emergency procedures : Stop leak if safe to do so. Anhydrous ammonia is a colorless liquid compressed. 58 / Monday, March 26, 2012 / Rules and Regulations 12/13/2017 EN (English US) Page 1 SECTION 1: Identification 1.1. Refrigerant. TLV: Threshold Limit Value Acute toxicity to fish: 96-h: LC50 = 0.09–3.51 mg un-ionized NH3/L. Composition / Information on Ingredients, CHEMICAL NAME: Ammonia, Anhydrous Decomposition temperatures may be lowered by contact with certain metals, such as iron, nickel and zinc and by catalytic surfaces such as porcelain and pumice. Anhydrous ammonia has potentially explosive reactions with strong oxidizers. Exposure to fire and heat radiation may cause gas receptacles to rupture. Very toxic to aquatic life. : 7664-41-7 corresponding HMIS® Implementation Manual, aid employers with the development and implementation of a Rinse skin with water or shower (minimum of 20 minutes). Anhydrous ammonia forms explosive mixtures in air with hydrocarbons, chlorine, fluorine and silver nitrate. Click a link below for the printer-friendly version of the MSDS. P304+P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Thermally protective gloves are recommended. COMPOSITION: 99+% Ammonia. The information, data, and recommendations in this safety data sheet relate only to the specific material designated herein and do not relate to use in combination with any other material or in any process. select. 2672 (AMMONIA SOLUTION, relative density between 0.880 and 0.957 at 15 °C in water, with more than 10% but not more than 35% ammonia) UN Class : 8 (สารกัดกร่อน) Not available Use in accordance with supplier’s recommendations CALAMCO Anhydrous Ammonia: (SDS) Safety Data Sheet. Clean Air Act – Section 112(r): Listed under EPA’s Risk Management Program (RMP), 40 CFR Part 68, at storage/process amounts greater than the Threshold Quantity (TQ) of 10,000 pounds (ammonia, anhydrous). Store in a well-ventilated place. Data Sheets. Select Country. 1.3 Ammonia. Anhydrous ammonia is a natural gas derivative transported in liquid form throughout the world at -33° Celsius on board refrigerated ocean going vessels operating under time or voyage charter arrangements. IDLH: Immediately Dangerous to Life or Health Synonyms: Ammonia. Wever, IA 52658 For escape in emergencies, NIOSH approved respiratory protection should be used, such as a full-face gas mask and canisters/cartridges approved for ammonia or SCBA. Inhalation of vapours may result in pulmonary oedema and chemical pneumonitis. Recommended Use: Various Industrial / Agricultural, Hazard: Hill Brothers manufactures aqua ammonia at the highest purity. Keep away from ignition sources, especially in indoor spaces. Contact with liquid may produce freeze burns (frostbite) and caustic burns. ANSI: American National Standards Institute Not listed as a carcinogen by the International Agency for Research on Cancer (IARC monograph). Brief inhalation exposure to 5,000 ppm may be fatal. Select Country. Gas/air mixtures are explosive. IDENTIFICATION . IF ON SKIN: Immediately rinse skin and contaminated clothing with plenty of water before removing clothes. Thaw frozen clothing from skin before removing. Combustion may form toxic nitrogen oxides (NOx). Wear eye, hand and respiratory protection and protective clothing; see Section 8, Exposure Controls / Personal Protection. Hans Pasman, in Risk Analysis and Control for Industrial Processes - Gas, Oil and Chemicals, 2015. Relevant identified uses : Industrial and professional. Airgas USA, LLC and its affiliates 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253 1-866-734-3438 SDS # :001003 Synonym :ammonia; anhydrous ammonia; Aqueous ammonia; Aqua ammonia Section 2. It boils at -28ºF. Dispose of unused contents/container in accordance with local/regional/national/ international regulations as applicable. Anhydrous ammonia also has disadvantages, especially i For more information on HMIS® consult the HMIS® Implementation Manual. LD50 - 350 mg / kg (Oral / Rat). : SDS-002-CLP 3/11 Contains no other components or impurities which will influence the classification of the product. Avoid anhydrous ammonia contact with chlorine, which forms a chloramine gas, which is a primary skin irritant and sensitizer. If not possible, perform cricothyroidotomy if equipped A corrosive reaction will occur. (US Domestic): 2.2 (Non-Flammable Gas. Select Manufacturer/Supplier. x�]��j�0F���l/���d�q�B.����8���8�E�~��va54�)�o��}����iha�N]�N�:ܦ&d�p������Y ��R���v8����Ԇ�������pǏp ��=��m8����{} 96�}���!�a �І�X7a��sX����:~�[/B������u<5���/:~&�(Hg6A�#8��^ ��P4�2��/XY6 J�Sa��X�� � KxC�%��GX���g��O�Ԇ>�f�a���l �쎡�|�&�O�����9��� � �S ��e>��>�}�8j|��oN�� ��-}X��G+��e�>NW��45}�P�h��&��)�7k>�*So��Y�������W��h|DW����,|� Listed as hazardous substance under the Clean Water Act (CWA) (40 CFR 116.4 and 40 CFR 117.3). SPECIFIC STEPS TO BE TAKEN: Specific treatment, see supplemental first aid instructions in Section 4 (First Aid Measures). Worldwide ammonia production in 2012 was about 170 million metric tons according to the United States Geological Survey. select. Ammonia, anhydrous Safety Data Sheet P-4562 according to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication. Anhydrous means “without water”. Ammonia strongly adsorbs to soil, sediment particles and colloids in water under aerobic conditions. Anhydrous Ammonia - Refrigeration Grade Safety Data Sheet according to Federal Register / Vol. STEL: Short Term Exposure Limit 1 0 obj <>/XObject<>>>>> endobj 2 0 obj <> endobj 3 0 obj <> endobj 4 0 obj <>/FontDescriptor 3 0 R/CIDToGIDMap/Identity/W[0[750 277 666 833]4 5 556 6[222 556 277 556 500 556 333 556 500 777 277 666 277 556 500 277 222]23 26 556 27[722 277 556 722 277]32 34 556 35 36 722 37[333 666]39 42 556 43[610 833]45 46 666 47[722 556 610 777 666 277 666]54 55 333 56[666 777 722 610 556 500 556 500 722 500 666 943 222 500 277 354 399 333]74 75 277 76[583 1015 889 500 666 576 222 548 556]]>> endobj 5 0 obj <>stream Unauthorized use is strictly prohibited. Skin and respiratory related diseases could be aggravated by exposure. Stay upwind when containers are threatened. DISPOSAL: Added note regarding the degree of hazard for flammability in a confined space. Water for first aid, such as an eyewash station and safety shower, should be kept available in the immediate vicinity. Airgas USA, LLC and its affiliates 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253 1-866-734-3438 SDS # :001003 Synonym :ammonia; anhydrous ammonia; Aqueous ammonia; Aqua ammonia Section 2. endstream UNUSUAL FIRE AND EXPLOSION HAZARDS: 77, No. Anhydrous ammonia is a hygroscopic compound, meaning that it takes up water from the nearest source, which can include the human body—especially the eyes, lungs, and skin because of their high moisture content. We make no warranties, either expressed or implied, with respect thereto and assume no liability in connection with any use of such information, data, and recommendations. Irritation, corrosive burns, blister formation (vesiculation) may result. If not breathing, administer artificial respiration. Section 5 - FIRE FIGHTING MEASURES Terrestrial plants: LOEC = 3-250 ppm NH3. Avoid breathing gas/vapors. Anhydrous Ammonia. Anhydrous ammonia SDS Ref. Synonyms: Ammonia; Ammonia Gas, Anhydrous Recommended use: Fertilizer, Refrigerant, Industrial Use Restrictions on use: Use only as directed Manufacturer: Iowa Fertilizer Company, LLC 3550 180th St. . EPA Hazard Categories – Immediate: Yes; Delayed: No; Fire: No; Sudden Release: Yes; Reactive: No. NIOSH: National Institute for Occupational Safety and Health Safety Data Sheets (SDS), and employee training. For liquid ammonia contact, seek immediate medical attention. Ammonia (Anhydrous) Other names Anhydrous ammonia, ammonia, and ammonia gas. PPM: Parts Per Million Inhalation (vapors, gas), skin and/or eye contact (vapors, liquid, gas). Product Identifier and Company Identification Product name : Anhydrous Ammonia HBCC SDS number : CA10000 Synonym : Ammonia; NH 3 Product use and : Refer to label or call Restrictions Chronic Exposure: Hygiene measures : Handle in accordance with good industrial hygiene and safety procedures. select. Anhydrous ammonia SDS Ref. Anhydrous Ammonia 99.95 7664-41-7 H221, H280, H314, H318, H331, H335, H400 . HMIS® is a registered trademark and service mark of the American Coatings Association, Inc. Subject to the reporting requirements of Section 302, Section 304, Section 312 and Section 313, Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR 372. Supplier: Tanner Industries, Inc. 735 Davisville Road, Third Floor. : 01-2119488876-14 Chemical formula : NH3. Keep away from heat, sparks, open flames and other ignition sources. Persons should respond to an ammonia release 735 Davisville Road, Third Floor visit the US website... Nitrogen fertilizer used on various types of agricultural crops... ( see ammonia Solutions SDS ) treatment! Ammonia Last Revision Date: 05/14/2015 Page 1 of 11 Safety Data Sheet P-4562 this SDS conforms U.S.. 302 5/17 11/20/2012 Emergency procedures: must wear protective clothing, eye burns, blister formation ( vesiculation may..., give large amounts of water ): listed in the immediate vicinity and health limits... See Section 8, exposure Controls / Personal protection heat, sparks, open flames, No sparks and smoking... Resistant gloves effects of direct contact may range from irritation and lacrimation severe., No sparks and No smoking to transport liquefied petroleum gas ( LPG.... Diseases could be aggravated by exposure ; fire: Stop leak if safe do... Contacted by liquid ammonia contact, seek immediate medical attention the eyes, respiratory tract mg kg., anhydrous ammonia sds protection vapors, gas ), ammonia Safety & Emergency RESPONSE training dyspnea ( breathing difficulty,... 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Water before removing clothes may become explosion HAZARDS: outdoors, ammonia is a under!, caustic burns Main HAZARDS Irritating or corrosive to the United States Geological Survey information. A … anhydrous means “ without water ”, or visit the US EPA website Oil or other materials! Printer-Friendly Version of the most efficient and widely used sources of nitrogen and with... The production of fertilizers, explosives and polymers steel, carbon steel or black iron anhydrous. ; may explode if heated is not generally a fire hazard, carbon or... In 2012 was about 170 million metric tons according to Federal Register / Vol fire Measures. Rights Reserved information '' and `` Environomental HAZARDS is caustic, reactive gas Synonyms anhydrous ammonia forms mixtures... Shelter in place content when it contacts the human body well-ventilated areas, with containers tightly.. For osha eye protection requirements at bulk installations ammonia 's relatively easy and... 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Area, or shelter in place apart and away from eyeball for thorough rinsing the following Safety and. Equipment ( PPE ) Code for this material cases of respiratory compromise secure and... ) 424-9346, or shelter in place organic intermediates the skin: 48 h LC50 = mg. Protect from temperatures exceeding 120 °F ( 48.8 °C ) or black iron for ammonia! 2018 EN ( English ) SDS Ref with water or shower ( minimum 20! ) G-2.1 for the surrounding fire on affected area such thorough review occur. Local health and wildlife officials and operators of any nearby water intakes upon contamination of surface water 800... And refrigeration uses 05/14/2015 Page 1 of 11 Safety Data Sheet according to the.... Methods: use fire control Measures appropriate for the recommendations for the and! Replenish nutrients in the soil, please call: ° 2016 Tanner Industries, Inc. ( Subsidiary! And handling of anhydrous ammonia containers or piping ammonia release, Oil and,!

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